有機合成用金属触媒
Metal Catalysts for Organic Synthesis

均一系金属触媒 / Homogeneous Catalysts

不均一系金属触媒 / Heterogeneous Catalysts

均一系金属触媒 / Homogeneous Catalysts

T1548 T1548
T1548 Lithium Trifluoromethanesulfonate
T1550 T1550
T1550 Sodium Trifluoromethanesulfonate
T1304 T1304
T1304 Magnesium Trifluoromethanesulfonate
A0246 A0246 A0804 A0804 E0648 E0648
M1211 M1211 A0241 A0241 A1267 A1267
A0246 Aluminum Isopropoxide
A0804 Aluminum tert-Butoxide
E0648 Ethylaluminum Dichloride (17% in Hexane, ca. 1mol/L)
M1211 Methylaluminum Bis(2,6-di-tert-butyl-4-methylphenoxide) (0.4mol/L in Toluene)
A0241 Tris(2,4-pentanedionato)aluminum(III)
A1267 Tris(trifluoro-2,4-pentanedionato)aluminum(III)
T1549 T1549
T1549 Potassium Trifluoromethanesulfonate
T1663 T1663
T1663 Scandium(III) Trifluoromethanesulfonate
I0646 I0646 P1651 P1651 C1994 C1994
D2257 D2257 B0742 B0742 T0967 T0967
T0978 T0978 T0133 T0133 T0666 T0666
B1588 B1588
I0646 (Indenyl)titanium(IV) Trichloride
P1651 (Pentamethylcyclopentadienyl)titanium(IV) Trichloride
C1994 Cyclopentadienyltitanium(IV) Trichloride
D2257 Dichlorotitanium Diisopropoxide
B0742 Tetrabutyl Orthotitanate
T0967 Tetraethyl Orthotitanate
T0978 Tetraisobutyl Orthotitanate (contains Isopropoxide)
T0133 Tetraisopropyl Orthotitanate
T0666 Tetraoctadecyl Orthotitanate
B1588 [1,2-Benzenediolato(2-)-O,O']oxotitanium
C0336 C0336
C0336 Tris(2,4-pentanedionato)chromium(III)
B2409 B2409 M0042 M0042 H0557 H0557
T0685 T0685
B2409 (1S,2S)-N,N'-Bis[(R)-2-hydroxy-2'-phenyl-1,1'-binaphthyl-3-ylmethylene]-1,2-diphenylethylenediaminato Manganese(III) Acetate
M0042 Bis(2,4-pentanedionato)manganese(II) Dihydrate
H0557 Bis(hexafluoroacetylacetonato)manganese(II) Hydrate
T0685 Bis(trifluoro-2,4-pentanedionato)manganese(II)
D2571 D2571 I0079 I0079 T1686 T1686
H0555 H0555 T0750 T0750
D2571 N,N'-Bis(salicylidene)ethylenediamine Iron(II)
I0079 Tris(2,4-pentanedionato)iron(III)
T1686 Tris(dibenzoylmethanato) Iron
H0555 Tris(hexafluoroacetylacetonato)iron(III)
T0750 Tris(trifluoro-2,4-pentanedionato)iron(III)
B2314 B2314 B1844 B1844 B2315 B2315
B1845 B1845 B2681 B2681 C0373 C0373
H0553 H0553 T0746 T0746 D3213 D3213
S0318 S0318 C0374 C0374
B2314 (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
B1844 (1R,2R)-N,N'-Bis[3-oxo-2-(2,4,6-trimethylbenzoyl)butylidene]-1,2-diphenylethylenediaminato Cobalt(II)
B2315 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
B1845 (1S,2S)-N,N'-Bis[3-oxo-2-(2,4,6-trimethylbenzoyl)butylidene]-1,2-diphenylethylenediaminato Cobalt(II)
B2681 Bis(2,4-pentanedionato)cobalt(II)
C0373 Bis(2,4-pentanedionato)cobalt(II) Dihydrate
H0553 Bis(hexafluoroacetylacetonato)cobalt(II) Hydrate
T0746 Bis(trifluoro-2,4-pentanedionato)cobalt(II)
D3213 Dicobalt Octacarbonyl
S0318 Salcomine [=N,N'-Bis(salicylidene)ethylenediiminocobalt(II)]
C0374 Tris(2,4-pentanedionato)cobalt(III)
N0096 N0096 H0558 H0558 B1571 B1571
B3354 B3354 B2226 B2226 B2225 B2225
B1313 B1313
N0096 Bis(2,4-pentanedionato)nickel(II) Hydrate
H0558 Bis(hexafluoroacetylacetonato)nickel(II) Hydrate
B1571 Bis(triphenylphosphine)nickel(II) Dichloride
B3354 Bromo[(2,6-pyridinediyl)bis(3-methyl-1-imidazolyl-2-ylidene)]nickel Bromide
B2226 [1,1'-Bis(diphenylphosphino)ferrocene]nickel(II) Dichloride
B2225 [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride
B1313 [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride
C0384 C0384 H0554 H0554 T0752 T0752
T1442 T1442 T1292 T1292 D2542 D2542
C0384 Bis(2,4-pentanedionato)copper(II)
H0554 Bis(hexafluoroacetylacetonato)copper(II) Hydrate
T0752 Bis(trifluoro-2,4-pentanedionato)copper(II)
T1442 Copper(I) Trifluoromethanesulfonate Benzene Complex
T1292 Copper(II) Trifluoromethanesulfonate
D2542 Di-mu-hydroxo-bis[(N,N,N',N'-tetramethylethylenediamine)copper(II)] Chloride
Z0002 Z0002 T1294 T1294
Z0002 Bis(2,4-pentanedionato)zinc(II)
T1294 Zinc(II) Trifluoromethanesulfonate
T1921 T1921
T1921 Yttrium(III) Trifluoromethanesulfonate
C1995 C1995 Z0006 Z0006 T0747 T0747
Z0009 Z0009
C1995 Cyclopentadienylzirconium(IV) Trichloride
Z0006 Tetrakis(2,4-pentanedionato)zirconium(IV)
T0747 Tetrakis(trifluoro-2,4-pentanedionato)zirconium(IV)
Z0009 Zirconocene Bis(trifluoromethanesulfonate) Tetrahydrofuran Adduct
M0464 M0464
M0464 Bis(2,4-pentanedionato)molybdenum(VI) Dioxide
P1688 P1688 H1010 H1010 B1902 B1902
D2751 D2751 R0074 R0074 T1559 T1559
T1655 T1655 T2183 T2183 D1997 D1997
B3067 B3067 B3068 B3068
P1688 (3-Phenyl-1H-inden-1-ylidene)bis(tricyclohexylphosphine)ruthenium(IV) Dichloride Tetrahydrofuran Adduct
H1010 (Hexamethylbenzene)ruthenium(II) Dichloride Dimer
B1902 Benzeneruthenium(II) Chloride Dimer
D2751 Dichloro(p-cymene)ruthenium(II) Dimer
R0074 Ruthenium(III) Chloride
T1559 Tetrapropylammonium Perruthenate
T1655 Tris(2,2'-bipyridyl)ruthenium(II) Chloride Hexahydrate
T2183 Tris(2,4-pentanedionato)ruthenium(III)
D1997 Tris(triphenylphosphine)ruthenium(II) Dichloride
B3067 [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
B3068 [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
P1788 P1788 B2090 B2090 B2091 B2091
B1692 B1692 C1383 C1383 B1045 B1045
C2253 C2253 N0453 N0453 R0069 R0069
T1544 T1544 T2054 T2054 T1551 T1551
T2055 T2055 T2658 T2658 T2659 T2659
T2660 T2660 T2661 T2661 T0931 T0931
P1788 (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer
B2090 (S,S)-1,2-Bis[(tert-butyl)methylphosphino]ethane[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate
B2091 Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate
B1692 Carbonylbis(triphenylphosphine)rhodium(I) Chloride
C1383 Carbonyltris(triphenylphosphine)rhodium(I) Hydride
B1045 Chloro(1,5-cyclooctadiene)rhodium(I) Dimer
C2253 Chlorobis(cyclooctene)rhodium(I) Dimer
N0453 Norbornadiene Rhodium(I) Chloride Dimer
R0069 Rhodium(II) Acetate Dimer
T1544 Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct
T2054 Tetrakis[N-phthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
T1551 Tetrakis[N-phthaloyl-(S)-phenylalaninato]dirhodium Ethyl Acetate Adduct
T2055 Tetrakis[N-phthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
T2658 Tetrakis[N-tetrachlorophthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
T2659 Tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
T2660 Tetrakis[N-tetrafluorophthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
T2661 Tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct
T0931 Tris(triphenylphosphine)rhodium(I) Chloride
A1479 A1479 B2029 B2029 B2018 B2018
B1676 B1676 B1668 B1668 B1374 B1374
B2161 B2161 B2026 B2026 B3161 B3161
B2055 B2055 B2042 B2042 B1667 B1667
B3224 B3224 C2407 C2407 C2387 C2387
C2406 C2406 C2372 C2372 D3847 D3847
D2604 D2604 A1424 A1424 P1489 P1489
S0540 S0540 T1350 T1350 T2184 T2184
B3160 B3160 B2064 B2064 B2016 B2016
B2192 B2192 B2031 B2031
A1479 Allylpalladium(II) Chloride Dimer
B2029 Benzylbis(triphenylphosphine)palladium(II) Chloride
B2018 Bis(2,4-pentanedionato)palladium(II)
B1676 Bis(acetonitrile)palladium(II) Dichloride
B1668 Bis(benzonitrile)palladium(II) Dichloride
B1374 Bis(dibenzylideneacetone) Palladium(0)
B2161 Bis(methyldiphenylphosphine)palladium(II) Dichloride
B2026 Bis(tri-o-tolylphosphine)palladium(II) Dichloride
B3161 Bis(tri-tert-butylphosphine)palladium(0)
B2055 Bis(tricyclohexylphosphine)palladium(II) Dichloride
B2042 Bis(triphenylphosphine)palladium(II) Diacetate
B1667 Bis(triphenylphosphine)palladium(II) Dichloride
B3224 Bis[1,2-bis(diphenylphosphino)ethane]palladium(0)
C2407 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](4'-methoxyacetanilide)palladium(II)]
C2387 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](acetanilide)palladium(II)]
C2406 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](N,N-dimethyl-3,5-dimethoxybenzylamine)palladium(II)]
C2372 Chloro[[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](N,N-dimethylbenzylamine)palladium(II)]
D3847 Di-mu-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)
D2604 Dichloro(1,5-cyclooctadiene)palladium(II)
P1430 Palladium Catalyst Set Palladium(II) Acetate / Allylpalladium(II) Chloride Dimer / Bis(benzonitrile)palladium(II) Dichloride / Bis(dibenzylideneacetone)palladium(0) / [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride / Bis(triphenylphosphine)palladium(II) Dichloride / Tetrakis(triphenylphosphine)palladium(0) (includes useful 7 Palladium catalysts)
A1424 Palladium(II) Acetate
P1489 Palladium(II) Chloride
S0540 Sodium Tetrachloropalladate(II)
T1350 Tetrakis(triphenylphosphine)palladium(0)
T2184 Tris(dibenzylideneacetone)dipalladium(0)
B3160 [1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride
B2064 [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct
B2016 [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
B2192 [1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride
B2031 [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride
C2373 C2373 T1331 T1331
C2373 Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver
T1331 Silver Trifluoromethanesulfonate
D2466 D2466 T1194 T1194
D2466 Dibutyltin Bis(trifluoromethanesulfonate)
T1194 Tin(II) Trifluoromethanesulfonate
T1918 T1918 T1293 T1293 T1919 T1919
T1920 T1920 L0148 L0148 T1610 T1610
T1918 Cerium(III) Trifluoromethanesulfonate
T1293 Lanthanum(III) Trifluoromethanesulfonate
T1919 Neodymium(III) Trifluoromethanesulfonate
T1920 Thulium(III) Trifluoromethanesulfonate
L0148 Tris(2,4-pentanedionato)lanthanum(III) Hydrate
T1610 Ytterbium(III) Trifluoromethanesulfonate Hydrate
T1708 T1708
T1708 Hafnium(IV) Trifluoromethanesulfonate
P1763 P1763 C1807 C1807
P1763 (Pentamethylcyclopentadienyl)iridium(III) Dichloride Dimer
C1807 Chloro(1,5-cyclooctadiene)iridium(I) Dimer
B3115 B3115 B3162 B3162 D3592 D3592
T2485 T2485
B3115 Bis(2,4-pentanedionato)platinum(II)
B3162 Bis(tri-tert-butylphosphine)platinum(0)
D3592 Dichloro(1,5-cyclooctadiene)platinum(II)
T2485 Tetrakis(triphenylphosphine)platinum(0)

不均一系金属触媒 / Heterogeneous Catalysts

P1490 P1490 P1491 P1491 P1701 P1701
P1702 P1702 P1703 P1703 P1785 P1785
P1528 P1528
P1490 Palladium 5% on Carbon (wetted with ca. 55% Water)
P1491 Palladium 10% on Carbon (wetted with ca. 55% Water)
P1701 Palladium 5% on Barium Carbonate
P1702 Palladium 5% on Barium Sulfate
P1703 Palladium 5% on Calcium Carbonate (poisoned with Lead)
P1785 Palladium 10% on Carbon (wetted with ca. 55% Water) [Useful catalyst for coupling reaction, etc.]
P1528 Palladium Hydroxide 20% on Carbon (wetted with ca. 50% Water)
P1786 Palladium on SH Silica Gel (0.1mmol/g)
R0075 Rhodium 5% on Carbon (wetted with ca. 55% Water)
R0076 Ruthenium 5% on Carbon (wetted with ca. 50% Water)
S0487 Skeletal Nickel Catalyst slurry in Water [Active catalyst for Hydrogenation]

ポリマー担持合成試薬 / Polymer-Supported Reagents

文献

1) C. Elschenbroich, J. Oliveira, in Organometallics, 3rd ed., Wiley-VCH, Weinheim, 2006.
2) Y. Murakami, J. Kikuchi, Y. Hisaeda, O. Hayashida, Chem. Rev., 1996, 96, 721 [DOI].


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